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ChemInform Abstract: Synthesis of Melithiazol B and Related Compounds via Oxidative Degradation of Myxothiazol A and Z.

✍ Scribed by Udo Soeker; Florenz Sasse; Brigitte Kunze; Gerhard Hoefle

Publisher
John Wiley and Sons
Year
2001
Weight
35 KB
Volume
32
Category
Article
ISSN
0931-7597

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Synthesis of Melithiazol B and Related C
Synthesis of Melithiazol B and Related Compounds via Oxidative Degradation of Myxothiazol A and Z
✍ Udo SΓΆker; Florenz Sasse; Brigitte Kunze; Gerhard HΓΆfle πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 248 KB πŸ‘ 2 views

The synthesis of melithiazol B (4) has been accomplished in five steps and 19% overall yield starting from myxothiazol A (1). Key steps include the conversion of the amide into the methyl ester 4, oxygenation to hydroperoxides 7 and 9, and