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ChemInform Abstract: Synthesis of Ketene N,N-Acetals by Copper-Catalyzed Double-Amidation of 1,1-Dibromo-1-alkenes.

✍ Scribed by Alexis Coste; Francois Couty; Gwilherm Evano

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Copper-Mediated Cro
ChemInform Abstract: Copper-Mediated Cross-Coupling of 1,1-Dibromo-1-alkenes with Dialkyl Phosphites: A Convenient Synthesis of 1-Alkenylphosphonates.
✍ Gwilherm Evano; Krishnaji Tadiparthi; Francois Couty πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 53 KB πŸ‘ 1 views

## Abstract The Hirao reduction of 1,1‐dibromo‐1‐alkenes with diisopropyl phosphite generates intermediate 1‐alkenylbromides, which react with a second equivalent phosphite to afford desired 1‐alkenylphoshonates.