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ChemInform Abstract: Synthesis of Isoxazole-Substituted β-Triketones in the Cyclohexane Series.

✍ Scribed by D. B. RUBINOV; I. L. RUBINOVA; A. A. AKHREM

Book ID
112025062
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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Transformations in the Isoxazole Series:
Transformations in the Isoxazole Series: Synthesis of Substituted 2-Aminothiazoles
✍ Alfons Pascual 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 German ⚖ 790 KB

Substitued N-(isoxazol-4-yl)thioureas 1 undergo a transformation in the presence of hexacarbonylmolybdenum and acid to yield functionalized thiazoles 3 in a one-pot reaction. In a few cases, 1,4,5-trisubstituted dihydroimidazoleth,iones 4 are also isolated as side products. Mechanistic consideration