## Abstract Unsymmetrical olefins react highly regioselectively with phenyl hydroxylamine.
ChemInform Abstract: Synthesis of Functionalized Oxazolones by a Sequence of Cu(II)- and Au(I)-Catalyzed Transformations.
β Scribed by Florin M. Istrate; Andrea K. Buzas; Igor Dias Jurberg; Yann Odabachian; Fabien Gagosz
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 47 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Au/AgβCatalyzed cycloisomerization of a variety of oβalkynylstyrene derivatives, e.g. (I) and (VII), proceeds with moderate to high enantioselectivity (up to 92% e.e.) in the presence of an axially chiral MeOβbiphep ligand to give alkenylβsubstituted indenes (II) and (VIII), resp., in h