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ChemInform Abstract: Synthesis of (E,Z)-1-Alkoxy-3-acyloxy-2-methylpenta-1,3-dienes via Danishefsky-Type Dienes or O-Acylation of Enones.

✍ Scribed by Sylvain Laclef; Claudia J. Exner; Maris Turks; Valeria Videtta; Pierre Vogel


Publisher
John Wiley and Sons
Year
2010
Weight
57 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Palladium-Catalyzed
✍ Xiaoyi Chen; Wei Kong; Haiting Cai; Lichun Kong; Gangguo Zhu πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 31 KB

## Abstract The palladium‐catalyzed haloallylation of alkynes (I) in dichloromethane leads stereoselectively to (E)‐dihalodienes (III), whereas (Z)‐isomers (IV) are readily obtained by the same reaction in acetic acid in the presence of lithium halides.