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ChemInform Abstract: Synthesis of Exocyclic Enamides via Stereocontrolled Allylic Isomerization and 1,3-Transposition.

โœ Scribed by Afzal Khan; Charles M. Marson; Rod A. Porter

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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1,3-Transposition of Allylic Alcohols Catalyzed by Methyltrioxorhenium. -The kinetics and theoretical calculations of the 1,3-rearrangement of allylic alcohols with MeReO 3 catalyst to generate the more stable isomer are studied. The direction of the equilibrium is largely influenced by the nature o