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ChemInform Abstract: Synthesis of (E)-α,β-Unsaturated Esters and Amides with Total Selectivity Using Samarium Diiodide.

✍ Scribed by Jose M. Concellon; Juan A. Perez-Andres; Humberto Rodriguez-Solla

Publisher: John Wiley and Sons
Year: 2000
Weight: 35 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200045038

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Synthesis of (E)-α,β-Unsaturated Esters

Synthesis of (E)-α,β-Unsaturated Esters and Amides with Total Selectivity Using Samarium Diiodide

✍ José M. Concellón; Juan A. Pérez-Andrés; Humberto Rodríguez-Solla 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 79 KB 👁 1 views

ChemInform Abstract: Synthesis of (E)-α,

ChemInform Abstract: Synthesis of (E)-α,β-Unsaturated Amides with High Selectivity by Using Samarium Diiodide.

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Synthesis of (E)-α,β-Unsaturated Amides

Synthesis of (E)-α,β-Unsaturated Amides with High Selectivity by Using Samarium Diiodide

✍ José M. Concellón; Juan A. Pérez-Andrés; Humberto Rodríguez-Solla 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 129 KB

Stereoselective b-elimination of 2-chloro-3-hydroxyamides 1 is achieved by using samarium diiodide to yield a,b-unsaturated amides 2, in which the C C bond is di-tri-, or tetrasubstituted. The starting compounds 1 are easily prepared by reaction of the corresponding lithium enolates of a-chloroamide

ChemInform Abstract: Synthesis of Isotop

ChemInform Abstract: Synthesis of Isotopically Labeled (E)-β,γ-Unsaturated Esters with Total or High E/Z—Selectivity by Using Samarium Diiodide.

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Synthesis of Aromatic (E)- or (Z)-α,β-Un

Synthesis of Aromatic (E)- or (Z)-α,β-Unsaturated Amides with Total or Very High Selectivity from α,β-Epoxyamides and Samarium Diiodide.

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Synthesis of (E)-α-Hydroxy-β,γ-Unsaturat

Synthesis of (E)-α-Hydroxy-β,γ-Unsaturated Amides with High Selectivity from α,β-Epoxyamides by Using Catalytic Samarium Diiodide or Triiodide

✍ José M. Concellón; Pablo L. Bernad; Eva Bardales 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB