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ChemInform Abstract: Synthesis of Diynes and Tetraynes from in situ Desilylation/Dimerization of Acetylenes.

✍ Scribed by Matthew A. Heuft; Shawn K. Collins; Glenn P. A. Yap; Alex G. Fallis

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: One-Pot Desilylatio
ChemInform Abstract: One-Pot Desilylation/Dimerization of Ethynyl- and Butadiynyltrimethylsilanes. Synthesis of Tetrayne-Linked Dehydrobenzoannulenes.
✍ M. M. HALEY; M. L. BELL; S. C. BRAND; D. B. KIMBALL; J. J. PAK; W. B. WAN πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB

## One-Pot Desilylation/Dimerization of Ethynyl-and Butadiynyltrimethylsilanes. Synthesis of Tetrayne-Linked Dehydrobenzoannulenes. -Addition of potassium carbonate to standard Eglinton oxidative dimerization conditions for silyl acetylenes (I) results in a one-pot desilylation/dimerization reac