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ChemInform Abstract: Synthesis of Cyclopentenones 2- and 2,4-Oxygenated from Furfural.

โœ Scribed by Natalia R. da F. e Silva; Gouvan C. de Magalhaes

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioconvergent S
ChemInform Abstract: Enantioconvergent Synthesis of (+)-Estrone from Racemic 4-tert-Butoxy- 2-cyclopentenone.
โœ T. SUGAHARA; K. OGASAWARA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB ๐Ÿ‘ 2 views

Enantioconvergent Synthesis of (+)-Estrone from Racemic 4-tert-Butoxy-2-cyclopentenone. -Starting from racemic cyclopentenone (I) (+)-estrone (XIII) is prepared in an enantioconvergent manner. Key steps are the lipase-mediated kinetic resolution of the alcohol (IV) and the Diels-Alder -retro-Diels-