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ChemInform Abstract: Stereoselective Synthesis of Polyfunctionalized Hydroxylated Cyclopentanes from Dihydroxylated 2-Cyclopentenone Derivatives.

✍ Scribed by S. Caddick; et al. et al.


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioconvergent S
✍ T. SUGAHARA; K. OGASAWARA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 1 views

Enantioconvergent Synthesis of (+)-Estrone from Racemic 4-tert-Butoxy-2-cyclopentenone. -Starting from racemic cyclopentenone (I) (+)-estrone (XIII) is prepared in an enantioconvergent manner. Key steps are the lipase-mediated kinetic resolution of the alcohol (IV) and the Diels-Alder -retro-Diels-