ChemInform Abstract: Synthesis of Chiral α-Alkoxyketones via Allene Oxides.
✍ Scribed by M. SHIPMAN; H. R. THORPE; I. R. CLEMENS
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
## Abstract The α‐methoxyketones are prepared via deprotonation of the starting propylidene amine (I) with LDA, followed by reaction with alkyl halides and hydrolysis of the imino functionality.
## Abstract α‐Alkoxy allenes are smoothly converted into α′‐alkoxy enones by oxidation with m‐chloroperbenzoic acid.
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