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ChemInform Abstract: New General Synthesis of α-Alkoxyketones via α′-Alkylation, α-Alkylation and α,α′-Dialkylation of α-Alkoxyketimines.

✍ Scribed by Filip Colpaert; Sven Mangelinckx; Maria Teresa Rocchetti; Norbert De Kimpe

Publisher
John Wiley and Sons
Year
2011
Weight
52 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The α‐methoxyketones are prepared via deprotonation of the starting propylidene amine (I) with LDA, followed by reaction with alkyl halides and hydrolysis of the imino functionality.

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