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ChemInform Abstract: Synthesis of Chiral 2-Aroyl-1-tetralols: Asymmetric Transfer Hydrogenation of 2-Aroyl-1-tetralones via Dynamic Kinetic Resolution.

✍ Scribed by Yun Wu; Zhicong Geng; Jinjin Bai; Yawen Zhang


Publisher
John Wiley and Sons
Year
2011
Weight
30 KB
Volume
42
Category
Article
ISSN
0931-7597

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Synthesis of Chiral 2-Aroyl-1-tetralols:
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The dynamic kinetic resolution of 2-aroyl-1-tetralones was achieved via asymmetric transfer hydrogenation using (S,S)-RuCl(p-cymene)TsDPEN (TsDPEN = N-(tosyl)-1,2-diphenylethylenediamine) in formic acid/triethylamine (5∢2, molar ratio), afforded the desired products in good yields (up to 85%) with d

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v