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ChemInform Abstract: Synthesis of Chiral 1,3-Disubstituted Tetrahydroisoquinolines and Their Use in the Asymmetric Addition of Diethylzinc to Aldehydes.

✍ Scribed by Patricia D. MacLeod; Amy M. Reckling; Chao-Jun Li

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
41
Category
Article
ISSN
0931-7597

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## Abstract Optically active new pyridyl alcohols **1–4**, which can be easily synthesized by the reaction of (+)‐camphor or (βˆ’)‐menthone with lithiated pyridine derivatives, were applied as chiral ligands in the asymmetric addition of diethylzinc to aldehydes. Good yields with up to 94.0%enantiome