ChemInform Abstract: Synthesis of (+)-Casuarine.
โ Scribed by Scott E. Denmark; Alexander R. Hurd
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Synthesis of Casuarines (Pentahydroxylated Pyrrolizidines) by Sodium Hydrogen Telluride-Induced Cyclizations of Azidodimesylates. -The first synthesis of diastereomers (cf. (IX); 4 examples) of the very highly functionalized alkaloid, casuarine (X), is reported. Key step is the efficient reduction o
The ke]ยข ste~. in the slcn~esis of four ~te~.me~ of c.asuarine from eight carbon sugar laetones !s. me erttctent reo.ucaon o[ open c n~un azl.oodimesylates by sodium hydrogen ~ll~.de [Suz~'-T.~.oka reducuonlo~ aUow ~ rormauon, of the pyrroli~dine nucleus by oicyctisation. This ts me nrst report oz m