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Synthesis of casuarines [pentahydroxylated pyrrolizidines] by sodium hydrogen telluride-induced cyclisations of azidodimesylates

✍ Scribed by Andrew A. Bell; Lea Pickering; Alison A. Watson; Robert J. Nash; Yuan T. Pan; Alan D. Elbein; George W.J. Fleet

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
316 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

The ke]¢ ste~. in the slcn~esis of four ~te~.me~ of c.asuarine from eight carbon sugar laetones !s. me erttctent reo.ucaon o[ open c n~un azl.oodimesylates by sodium hydrogen ~ll~.de [Suz~'-T.~.oka reducuonlo~ aUow ~ rormauon, of the pyrroli~dine nucleus by oicyctisation. This ts me nrst report oz me synmests ot sucn mgmy oxygenateo pyrrolizidiues.

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