ChemInform Abstract: Synthesis of C-Glycosyl Lactones and Protected C-Glycosyl Amino Acids: Use of Radical Cyclization.
β Scribed by Junhu Zhang; Derrick L. J. Clive
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Diastereoselective Synthesis of C-Glycosylphosphonates via Free-Radical Glycosylation. -C-glycosidic sugar phosphonates (III) are prepared in a single step by addition of free radicals derived from the bromides (I) to dialkyl vinylphosphonates. In most cases, high Ξ±-selectivity at the reaction cent