ChemInform Abstract: Synthesis of Benzylpalladium Complexes Through C—O Bond Cleavage of Benzylic Carboxylates: Development of a Novel Palladium-Catalyzed Benzylation of Olefins.
✍ Scribed by Hirohisa Narahashi; Isao Shimizu; Akio Yamamoto
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 34 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of Oxygen Heterocycles via a Palladium-Catalyzed C-O Bond-Forming Reaction. -The first synthesis of cyclic aryl ethers by an intramolecular Pd-catalyzed ipso substitution of an aryl halide with an alcohol is described. This process is functional group tolerant and produces five-, six-, an