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ChemInform Abstract: Synthesis of Oxygen Heterocycles via a Palladium-Catalyzed C-O Bond- Forming Reaction.

✍ Scribed by M. PALUCKI; J. P. WOLFE; S. L. BUCHWALD

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199707150

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✦ Synopsis

Synthesis of Oxygen Heterocycles via a Palladium-Catalyzed C-O Bond-Forming Reaction.

-The first synthesis of cyclic aryl ethers by an intramolecular Pd-catalyzed ipso substitution of an aryl halide with an alcohol is described. This process is functional group tolerant and produces five-, six-, and seven-membered heterocycles in good yield. -(PALUCKI,

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