ChemInform Abstract: Synthesis of Benzo-Fused 1-Azabicyclo[m.n.0]alkanes via the Schmidt Reaction: A Formal Synthesis of Gephyrotoxin.
✍ Scribed by William H. Pearson; Wen-kui Fang
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 34 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A New [4 + 2] Cycloaddition Strategy for the Synthesis of N-Acyl-7-azabicyclo[2.2.1]heptan-2-ones: A Formal Synthesis of (±)-Epibatidine. -The title compound (VIII), an intermediate for the preparation of (±)-epibatidine, is prepared via Diels-Alder reaction of allenes with N-acylated pyrrole (II)
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract DBU‐promoted alkylation of cyclic α‐nitroketones (I) with o‐bromobenzyl halides, e.g. (II), (V) or (VIII), followed by Pd‐catalyzed intramolecular C‐arylation provides an efficient access towards benzo‐fused bicyclo[n.3.1]alkane derivatives (III), (VI) and (IX), respectively.