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ChemInform Abstract: Synthesis of Aryl Stannanes from Silyl Triflates via Aryne Intermediates.

✍ Scribed by B. Vasantha Lakshmi; Ulrike K. Wefelscheid; Uli Kazmaier

Publisher
John Wiley and Sons
Year
2011
Weight
49 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Treatment of silyl triflates with KF in the presence of 18‐crown‐6 generates aryne intermediates which undergo hydrostannation to give a mixture of regioisomeric aryl stannanes.

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