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ChemInform Abstract: Biaryl and Aryl Ketone Synthesis via Pd-Catalyzed Decarboxylative Coupling of Carboxylate Salts with Aryl Triflates.

โœ Scribed by Lukas J. Goossen; Christophe Linder; Nuria Rodriguez; Paul P. Lange

Publisher
John Wiley and Sons
Year
2010
Weight
59 KB
Volume
41
Category
Article
ISSN
0931-7597

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Biaryl and Aryl Ketone Synthesis via Pd-
Biaryl and Aryl Ketone Synthesis via Pd-Catalyzed Decarboxylative Coupling of Carboxylate Salts with Aryl Triflates
โœ Lukasโ€…J. Goossen; Christophe Linder; Nuria Rodrรญguez; Paulโ€…P. Lange ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 853 KB

## Abstract A bimetallic catalyst system has been developed that for the first time allows the decarboxylative crossโ€coupling of aryl and acyl carboxylates with aryl triflates. In contrast to aryl halides, these electrophiles give rise to nonโ€coordinating anions as byproducts, which do not interfer