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ChemInform Abstract: Synthesis of (+)- and (-)-Phaseolinic Acid by Combination of Enzymatic Hydrolysis and Chemical Transformations with Revision of the Absolute Configuration of the Natural Product.

✍ Scribed by S. DRIOLI; F. FELLUGA; C. FORZATO; P. NITTI; G. PITACCO; E. VALENTIN

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis of (+)-and (-)-Phaseolinic Acid by Combination of Enzymatic Hydrolysis and Chemical Transformations with Revision of the Absolute Configuration of the Natural Product. -The key step in the synthesis of the title acids is the enzymatic resolution of the ester (V). Naturally occurring phaseolinic acid possesses 2S,3S,4S configuration and not 2R,3R,4R as previously reported. -(DRIOLI, S.;

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