ChemInform Abstract: Total Synthesis and Absolute Configuration of the Natural Amino Acid Tetrahydrolathyrine (I).
β Scribed by Meryem Benohoud; Loic Leman; Silvia H. Cardoso; Pascal Retailleau; Philippe Dauban; Josiane Thierry; Robert H. Dodd
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 16 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Total Synthesis and Absolute Configuration of Polycavernoside A. -The first total synthesis of polycavernoside A (XII), a toxin of red alga species, is presented, involving formation of the cyclic acetal (IV), lactonization of secoic acid (V) and rearrangement of the obtained 12-membered lactone (V