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ChemInform Abstract: Synthesis of Aminoallenes via Reaction of α-Aminoalkylcuprates with Propargyl Substrates.

✍ Scribed by R. Karl Dieter; Lois E. Nice

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereospecific Coup
ChemInform Abstract: Stereospecific Coupling of α-Aminoalkylcuprates with Vinyl Iodides.
✍ R. K. DIETER; R. R. SHARMA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Stereospecific Coupling of α-Aminoalkylcuprates with Vinyl Iodides. -α-Aminoalkylcuprates, prepared from N-protected alkylamines (I) and (IV), sBuLi and LiCl solubilized CuCN, stereospecifically react with vinyl iodides (II) to the allylic amines (III) and (V). The iodoalkyne (IIc) can also be coup