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ChemInform Abstract: Stereospecific Coupling of α-Aminoalkylcuprates with Vinyl Iodides.

✍ Scribed by R. K. DIETER; R. R. SHARMA

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199747078

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✦ Synopsis

Stereospecific Coupling of α-Aminoalkylcuprates with Vinyl Iodides.

-α-Aminoalkylcuprates, prepared from N-protected alkylamines (I) and (IV), sBuLi and LiCl solubilized CuCN, stereospecifically react with vinyl iodides (II) to the allylic amines (III) and (V). The iodoalkyne (IIc) can also be coupled under these conditions. -(DIETER, R. K.;

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