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ChemInform Abstract: Synthesis of Acuminolide and 17-O-Acetylacuminolide from (+)-Sclareolide.

โœ Scribed by P. A. ZORETIC; H. FANG; A. A. RIBEIRO; G. DUBAY

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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In contrast to a recent result concerning the reaction of (I) and (II) in the presence of AgOTf a mixture of cyanoglycosylated products such as (IV)-(VII) is obtained. Diastereomers of (VI) and (VII) are also formed as by-products (2-4% yield). The structure of (V) is determined by X-ray analysis. M