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ChemInform Abstract: Synthesis of a New Class of Chiral 1,5-Diphosphanylferrocene Ligands and Their Use in Enantioselective Hydrogenation.

✍ Scribed by Tania Ireland; Katja Tappe; Gabi Grossheimann; Paul Knochel

Publisher: John Wiley and Sons
Year: 2010
Weight: 44 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200229040

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## P-Chiral Bis(trialkylphosphine) Ligands and Their Use in Highly Enantioselective Hydrogenation Reactions. -The title compounds, e.g. (I), prepared from alkyl dimethyl phosphine boranes using an asymmetric deprotonation (sBuLi/(-)-sparteine) and subsequent oxidative coupling as the key steps, a