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ChemInform Abstract: Synthesis of a Cyclitol via a Tandem Enzymatic Aldol - Intramolecular Horner-Wadsworth-Emmons Reaction.

✍ Scribed by H. J. M. GIJSEN; C.-H. WONG


Book ID
112025165
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: An Improved Synthes
✍ Sherry R. Chemler; D. Scott Coffey; William R. Roush 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

An Improved Synthesis of the (E,Z)-Dienoate Precursor of (+)-Damavaricin D via a Vinylogous Horner-Wadsworth-Emmons Reaction. -An improved synthesis of the title compound, the DmD intermediate (IV), is achieved by a (Z)-selective olefination of the aldehyde (III) using the vinylogous Horner-Wadswor