ChemInform Abstract: Synthesis of 6aλ4-Thia-1,2,4,6-tetraazapentalenes.
✍ Scribed by G. L'ABBE; P. VOSSEN; W. DEHAEN; L. VAN MEERVELT
- Book ID
- 112038604
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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6aX -Thia-l,fj-diazapentalenes have recently received interest' as a class of compounds with single-bond/no-bond resonance in comparison with the well-known 1,6,6aX -trithiapentalenes. The first preparation of such a compound (1) was described by Reid in 1969 and extensions to tri-( 2 ) and tetra-az
## 3-Methy1-6,7-dihydrc~-SH-l, 2,4-th iadiazolo[4,5-a] pyrimidine 4a reacted with isocyanates and isothiocyanates with elimination of acetonitrile and concomitant addition of two molecules of the heterocumubne togive the2,3-disubstituted-6,7-dihydro-SH-2ah4-thia-2, 3, 4a, ia-tetraazacyclopent[cd]