ChemInform Abstract: Synthesis of Polycy
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C. W. JEFFORD; H. ESCHENHOF; G. BERNARDINELLI
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Article
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2010
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John Wiley and Sons
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Synthesis of Polycyclic 1,2-Dioxanes from Endoperoxides. -Freshly prepared endoperoxides such as (I) undergo a Tms-O-Tf-catalyzed reaction with olefins (II) to give the 1,2-dioxane (III), albeit in low yield. However, the endoperoxide (IV) derived from 1,4-dimethylnaphthalene provides far more promi