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ChemInform Abstract: Synthesis of 6,13-Dithienylpentacenes by Photolysis of Their Endoperoxides.

โœ Scribed by Katsuhiko Ono; Takao Hiei; Mitsuhiro Tajika; Keijiro Taga; Katsuhiro Saito; Masaaki Tomura; Jun-ichi Nishida; Yoshiro Yamashita


Publisher
John Wiley and Sons
Year
2009
Weight
30 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of Polycy
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Synthesis of Polycyclic 1,2-Dioxanes from Endoperoxides. -Freshly prepared endoperoxides such as (I) undergo a Tms-O-Tf-catalyzed reaction with olefins (II) to give the 1,2-dioxane (III), albeit in low yield. However, the endoperoxide (IV) derived from 1,4-dimethylnaphthalene provides far more promi