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ChemInform Abstract: Synthesis of 6-Deoxyheptose Derivatives via Cyclic Sulfates and Oxetanes.

✍ Scribed by Antonio Vargas-Berenguel; Francisco Santoyo-Gonzalez; Jose A. Calvo-Asin; Francisco G. Calvo-Flores; Juan M. Exposito-Lopez; Fernando Hernandez-Mateo; Joaquin Isac-Garcia; Juan J. Gimenez Martinez


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Synthesis of 6-Deoxyheptose Derivatives via Cyclic Sulfates and Oxetanes.

-Two methods for chain elongation and synthesis of 6deoxyheptoses are detailed. The first approach is based on a regioselective opening of 4,6-cyclic sulfates [cf. (I)] and the second one involves a ring expansion of oxiranes to oxacyclobutanes.

-(VARGAS-BERENGUEL,


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