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ChemInform Abstract: Heterocyclization via 1,3-Cyclic Sulfates. Asymmetric Synthesis of (+)- Sedridine.

โœ Scribed by B. J. LITTLER; T. GALLAGHER; I. K. BODDY; P. D. RIORDAN

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of 6-Deox
ChemInform Abstract: Synthesis of 6-Deoxyheptose Derivatives via Cyclic Sulfates and Oxetanes.
โœ Antonio Vargas-Berenguel; Francisco Santoyo-Gonzalez; Jose A. Calvo-Asin; Franci ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

Synthesis of 6-Deoxyheptose Derivatives via Cyclic Sulfates and Oxetanes. -Two methods for chain elongation and synthesis of 6deoxyheptoses are detailed. The first approach is based on a regioselective opening of 4,6-cyclic sulfates [cf. (I)] and the second one involves a ring expansion of oxiranes