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ChemInform Abstract: Synthesis of 5- and 6-Chloropyridyl-Substituted 2-Azabicyclo[2.2.1]heptanes; Novel Epibatidine Isomers.

✍ Scribed by John R. Malpass; Caroline D. Cox

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199919242

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An Epoxide Rearrangement -Radical Rearrangement Approach to 6-Substituted 2-Azabicyclo[2.2.1]-5-heptenes: Synthesis of an Epibatidine Analogue. -Base-promoted isomerization of the epoxide (I) provides the azanortricyclanol (II). The latter can be readily converted to the derivatives (V) as precurso