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ChemInform Abstract: Synthesis of 4-Dialkylaminopyridine Derivatives Through Ring-Rearrangement of 3-Nitro-2H-pyran-2-one Acetamidines.

โœ Scribed by Vittorio Bertacche; Alessandro Contini; Emanuela Erba; Donatella Nava; Pasqualina Trimarco

Publisher
John Wiley and Sons
Year
2008
Weight
48 KB
Volume
39
Category
Article
ISSN
0931-7597

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Synthesis of Substituted 2-Amino-5-nitro-4H-pyran-3-carbonitriles. -The reaction of ฮฑ-nitroketone (I) with benzylidenemalononitriles (II) catalyzed by Et 3 N represents the first example of a synthesis of nitropyrans (III) from ฮฑ-nitroketones.