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ChemInform Abstract: Synthesis of 4-Aminocyclohex-1-enecarboxylates from Danishefsky′s Diene.

✍ Scribed by Josefina Quirante; Xavier Vila; Joseph Bonjoch

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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New Synthesis of Estradiol from Androsta-1,4-diene-3,17-dione. -A new method for the aromatization of ring A in androsta-1,4-diene-3,17-dione (I) via reduction to the corresponding dienediol (II) followed by double C,Odeprotonation of ring A is reported. This two-step transformation of (I) into est