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ChemInform Abstract: Synthesis of 3-Aminoindole Derivatives: Combination of Thorpe—Ziegler Cyclization and Unexpected Allylindium-Mediated Decyanation.

✍ Scribed by Yu Mi Kim; Ko Hoon Kim; Sunhong Park; Jae Nyoung Kim

Publisher
John Wiley and Sons
Year
2011
Weight
28 KB
Volume
42
Category
Article
ISSN
0931-7597

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Synthesis of 3-aminoindole derivatives:
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✍ Yu Mi Kim; Ko Hoon Kim; Sunhong Park; Jae Nyoung Kim 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 776 KB

a-Anilinonitriles were unexpectedly converted to 3-iminodihydroindoles via the Thorpe-Ziegler cyclization during the benzoylation. 3-Iminodihydroindoles were transformed to 3-aminoindoles in good yields via an allylindium-mediated decyanative aromatization.

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