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ChemInform Abstract: Synthesis of (-)-3-Amino-3-deoxyquinic Acid.

✍ Scribed by Michael Mueller; Rolf Mueller; Tin-Wein Yu; Heinz G. Floss

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis of (-)-3-Amino-3-deoxyquinic Acid.

-The title acid (X) is prepared in nine steps from quinic acid (I) in 14% overall yield. Its importance for the biosynthesis of 3-amino-5-hydroxybenzoic acid, the precursor of mC 7 N-units in ansamycin and mitomycin antibiotics is discussed.

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