Synthesis of the 3a-(3-Indolyl)-1,2,3,3a,8,8a-hexahydropyrrolo[2,3b]indole Core of Leptosins D-F. -The Fischer indole reaction of the previously reported L-tryptophan-derived aldehyde (I) with phenyl hydrazine in the presence of freshly fused zinc chloride provides the core unit (IV) of the leptosin
ChemInform Abstract: Synthesis of 2,3,6,8-Tetrahydroxybenzofuro[3,2-b][1]benzopyrylium Chloride (Riccionidin A).
β Scribed by G. DYKER; M. BAUER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
β¦ Synopsis
Synthesis
of 2,3,6,
[1]benzopyrylium Chloride (Riccionidin A).
-Presumably, the higher temperature in the synthesis of the title compound leads to cis/trans isomerization of the double bond. It forces the intramolecular condensation to (IV), a red to violet cell wall pigment found in liverworts. -(DYKER, G.; BAUER, M.;
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v