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ChemInform Abstract: Synthesis of 1,4-Diketones: Unusual Coupling of Tin Enolates with α-Chloro Ketones Catalyzed by Zinc Halides.

✍ Scribed by M. YASUDA; S. TSUJI; I. SHIBATA; A. BABA

No coin nor oath required. For personal study only.

✦ Synopsis

Synthesis of 1,4-Diketones: Unusual Coupling of Tin Enolates with α-Chloro Ketones Catalyzed by Zinc Halides.

-In the absence of zinc halides functionalized chlorohydrin derivatives such as (IV) are formed. -

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