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ChemInform Abstract: Synthesis of 1,3-Dialkyl-1,2,3-triazolium Ionic Liquids and Their Applications to the Baylis—Hillman Reaction.

✍ Scribed by Yunkyung Jeong; Jae-Sang Ryu

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
41
Category
Article
ISSN
0931-7597

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Synthesis of 2-Alkylidene-3,3-dialkyl-1,4-dithianes and Their Oxathiane Analogues by 1,2-Sulfur Migration. -Base-promoted mesylation of tertiary alcohols such as (I) and (III) derived from dithianes or oxathianes results in rearrangement by sulfur migration to yield the 1,4-dithianes (II) and their