ChemInform Abstract: Synthesis of 1,2,3,4,6-Penta-O-acetyl-5-deoxy-5-phenylphosphonothioyl- D-glucopyranoses.
β Scribed by T. HANAYA; A. AKAMATSU; T. ISONO; H. YAMAMOTO
- Book ID
- 112021698
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Treatment of 3-0-acetyl-5-deoxy-5-(dimethoxyphosphinyl)-l,2-O-isopropylidene-cr-D-glucofuranose (7) with dihydropyran in the presence of pyridinium ptoluenesulfonate gave the 6-0-(tetrahydropyran-2-yl) derivative in 91% yield. Ring-enlargement of this compound by the known, 2-step procedure gave 5-d
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