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ChemInform Abstract: Synthesis of 1,2-Bis(methoxyamino)cycloalkanes (VI) from Alicyclic 1,2- Bis(hydroxyamines).

✍ Scribed by D. G. MAZHUKIN; V. K. KHLESTKIN; A. YA. TIKHONOV; L. B. VOLODARSKII

Book ID: 112038870
Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199642091

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Stereoselective Synthesis of Cyclopropane-1,2-bis(glycine) Derivatives. -The synthesis of the title compounds (VII) and (VIII) is achieved via stereoselective azidation of the trans-cyclopropane derivative (III). Interestingly, under similar conditions the cis-isomer (IX) reacts differently yieldin