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ChemInform Abstract: Synthesis of 1-Methyl-4-alkyl-1,3-diacetylenes. Prototropic Rearrangement in 1-Alkyl-1,3-diacetylenes.

✍ Scribed by Miguel J. Dabdoub; Vania B. Dabdoub; Eder J. Lenardao

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200121076

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pyran derivatives pyran derivatives R 0340 42 -143 1-Alkyl-3,4-dihydro-thienopyran Acids and 1-Alkyl-3,4-dihydrobenzo[b]thienopyran Acids. -Ring closure of thienylethanols (I) and (IV) as well as their benzo analogues (VI) and (VIII) is achieved with oxo esters (II). The best results are obtained wi