For the first time, the (E)-1,2-difluoro-2-(pentafluorok 6 -sulfanyl)ethenyl group has been bonded to k 3 r 3 phosphorus using a Grignard reagent. Similar phosphorus derivatives containing the (Z)-1,2,3,3,3-pentafluoropropenyl moiety were also synthesized for comparison. In three cases, hexafluoroac
ChemInform Abstract: Synthesis, Crystal Structure, and Properties of 1,1,3,3,3-Pentaamino-1- thio-1λ5,3λ5-diphosphaz-2-ene (NH2)2P(S)N=P(NH2)3.
✍ Scribed by S. HORSTMANN; W. SCHNICK
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
The Reaction of P3N3Cl4(NH2)2 with HCl; Crystal Structure of P3N3Cl5( NH2). -The title compound (II) crystallizes in the triclinic space group P1 with Z = 2. (II), as well as (III) (obtained in another solvent) are further characterized by IR and Raman spectroscopy. The IR spectrum of (III) suggest