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ChemInform Abstract: Synthesis Based on Cyclohexadienes. Part 22. Formal Syntheses of Patchouli Alcohol and Norpatchoulenol.

✍ Scribed by K. P. KALIAPPAN; G. S. R. S. RAO

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis Based on Cyclohexadienes. Part 22. Formal Syntheses of Patchouli Alcohol and Norpatchoulenol.

-In continuation of a research programme concerning sesquiterpenes the formal synthesis of the title compounds such as (XIII) and (X) is performed via the key intermediates (XII) and (IX), respectively. The approach to these intermediates involves a Diels-Alder reaction to give (VI) and a catalytic hydrogenation to give (IX) and (XII) as the key steps. -(KALIAPPAN, K.

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