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ChemInform Abstract: Synthesis Based on Cyclohexadienes. Part 18. An Expedient Route to the Preparation of Key Intermediates for the Total Synthesis of Aphidacolin, Stemodin and Oryzalexin S.

✍ Scribed by K. KALIAPPAN; G. S. R. S. RAO

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199710154

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✦ Synopsis

Synthesis Based on Cyclohexadienes. Part 18. An Expedient Route to the Preparation of Key Intermediates for the Total Synthesis of Aphidacolin, Stemodin and Oryzalexin S. -Starting from 6-methoxy-1-tetralone (I) a method for the construction of tricyclo(6.3.1.01.6)dodecane (XI) and tricyclo(7.2.1.01.6)dodecane carbon skeleton present in several diterpenes is described. -(KALIAPPAN, K.; RAO, G.

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