## Synthesis and Structural Characterization of Gadolinium-Calcium Ferrites Gd 1-x CaxFeO 3-y (0 ≤ x ≤ 2/3). -Structure determination of the single phase title compounds, prepared by solid state reaction in air by powder XRD methods, shows that the perovskite-type compounds adopt the orthorhombic
✦ LIBER ✦
ChemInform Abstract: Synthesis and X-Ray Diffraction Studies of Dysprosium-Calcium Ferrites Dy1-xCaxFeO3-y (0 ≤ x ≤ 2/3).
✍ Scribed by J. LI; D. SONG; Z. SU; T. M. WANG
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Synthesis and X-Ray Diffraction Studies of Dysprosium-Calcium Ferrites Dy1-xCaxFeO3-y (0 ≤ x ≤ 2/3).
-The title compounds are prepared by solid state reaction of the binary oxides at 1200 • C in air (72 h). The obtained samples are single phase, orthorhombic compounds belonging to space group Pbnm ( powder XRD). The substitution of divalent Ca for trivalent Dy leads to a decrease of the unit cell dimensions up to x = 0.1; further substitution does not affect the unit cell volume. -(LI,
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