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ChemInform Abstract: Synthesis and Structures of Pyrroles Fused with Rigid Bicyclic Ring Systems at β-Positions.

✍ Scribed by Hidemitsu Uno; Satoshi Ito; Mitsuo Wada; Hikaru Watanabe; Miho Nagai; Akiko Hayashi; Takashi Murashima; Noboru Ono

Publisher: John Wiley and Sons
Year: 2001
Weight: 34 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200120090

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Asymmetric Mannich Synthesis of β-Amino Acids with Two New Stereogenic Centers at the α and β Positions. -The ZnCl2-catalyzed Mannich reaction of N-galactosyl aldimines, e.g. ( I), with ketene acetals as the C-nucleophiles furnishes β-amino acid derivatives, important building blocks of natural prod