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ChemInform Abstract: Preparation of α-Free Pyrroles with Perfluorinated Groups at β-Positions.

✍ Scribed by Hidemitsu Uno; Kentarou Inoue; Takashi Inoue; Yumiko Fumoto; Noboru Ono

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Mannich
ChemInform Abstract: Asymmetric Mannich Synthesis of β-Amino Acids with Two New Stereogenic Centers at the α and β Positions.
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Asymmetric Mannich Synthesis of β-Amino Acids with Two New Stereogenic Centers at the α and β Positions. -The ZnCl2-catalyzed Mannich reaction of N-galactosyl aldimines, e.g. ( I), with ketene acetals as the C-nucleophiles furnishes β-amino acid derivatives, important building blocks of natural prod